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Lady Anne Herbert is not the same as Ann Powell
Anne Herbert was the daughter of William Herbert, 1st Earl of Pembroke and Anne Herbert, Countess of Pembroke.
From link to A General and Heraldic Dictionary of the Peerage and Baronetage of ..., Volume 2 By John Burke Page 290
.... William Herbert, esq. who was installed a knight of the Garter in 1548, and elevated to the peerage, as Baron Herbert, of Cardiff, 10th October, 1551, and on the morrow created EARL. of PEMBROKE. His lordship m. first Anne, daughter of Thomas, Lord Parr, of Kendall, sister of King Henry the Eighth's last wife, Catherine Parr, and sister and co-heiress of William, Marquess of Northampton, by whom he had issue, H ENRY, his successor. Edward (Sir), of Powis Castle. Anne, m. to Francis, Lord Talbot, son and heir of George, sixth Earl of Shrewsbury. He m. secondly, Anne, daughter of George, fourth Earl of Shrewsbury, and widow of Peter Comptou, esq., but had no other issue. This earl was one of the most powerful noblemen of the period in which he lived. ...
From http://www.luminarium.org/encyclopedia/talbot6shrewsbury.htm
By his first wife Shrewsbury had issue: Francis, lord Talbot, who married, in 1562, Anne, daughter of William Herbert, first earl of Pembroke, but died in his father's lifetime;