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The first coin collector is said to have been Augustus. During the Renaissance, it became a fad among some members of the privileged classes, especially kings and queens.
A coin collector is different from a numismatist, which is someone who studies coins. Many collectors are also numismatists, but some are not. Likewise, not all numismatists collect coins themselves.
http://en.wikipedia.org/wiki/List_of_coin_collectors